Browsing Faculty of Science by Subject "Metal-free"
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Direct Brønsted acid-catalyzed functionalization of benzhydryl alcohols and 2-ethoxytetrahydrofuran using potassium trifluoroborate salts
(2016-06-01)Metal-free transformations of organotrifluoroborates are advantageous since they avoid using frequently expensive and sensitive transition metals. Lewis acid-catalyzed reactions involving organotrifluoroborates have emerged ... -
Metal-free methodology for the preparation of ynones using potassium alkynyltrifluoroborates and its application to the synthesis of natural products
(2015-03-01)A straightforward procedure for the preparation of ynones from potassium alkynyltrifluoroborate salts and acyl chlorides or anhydrides has been developed. The one-pot reaction is advantageous in that it does not require ...